The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs

• Main Authors: Heard, Peter *, Tan, Yee Seng *, Yeo, Chien Ing *, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: MDPI 2021
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1852/1/Tiekink%20Coordination%20Chemistry%20inorganics%202021%209%2071.pdf; http://eprints.sunway.edu.my/1852/; http://doi.org/10.3390/inorganics9090071
• Institution: Sunway University

A review of the coordination chemistry along with the structural features of heavy element complexes of dithiocarbimate di-anions in the form of [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class of compound is far less studied compared with the well-explored dithiocarbamate mono-an...