catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]

catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]

The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6...

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Main Authors: Arman, H.D., Miller, T., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12188/
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spelling my.um.eprints.121882019-01-31T01:10:26Z http://eprints.um.edu.my/12188/ catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate] Arman, H.D. Miller, T. Tiekink, E.R.T. Q Science (General) The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions. International Union of Crystallography 2010 Article PeerReviewed Arman, H.D. and Miller, T. and Tiekink, E.R.T. (2010) catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1212-U419. ISSN 1600-5368 (In Press)
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Arman, H.D.
Miller, T.
Tiekink, E.R.T.
catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
description The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions.
format Article
author Arman, H.D.
Miller, T.
Tiekink, E.R.T.
author_facet Arman, H.D.
Miller, T.
Tiekink, E.R.T.
author_sort Arman, H.D.
title catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
title_short catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
title_full catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
title_fullStr catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
title_full_unstemmed catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]
title_sort catena-poly[[[(2-pyridone-kappa o)silver(i)]l-mu-2-pyridone-kappa o-2/o] hexafluoridophosphate]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12188/
_version_ 1643689240199954432

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