Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted o...
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International Union of Crystallography
2010
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my.um.eprints.125292019-01-31T01:39:29Z http://eprints.um.edu.my/12529/ Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) Adrian, R.A. Gonzalez, D.M. Tiekink, E.R.T. Walmsley, J.A. Q Science (General) The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing. International Union of Crystallography 2010 Article PeerReviewed Adrian, R.A. and Gonzalez, D.M. and Tiekink, E.R.T. and Walmsley, J.A. (2010) Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M957-U903. ISSN 1600-5368 |
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Q Science (General) Adrian, R.A. Gonzalez, D.M. Tiekink, E.R.T. Walmsley, J.A. Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
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The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing. |
| format |
Article |
| author |
Adrian, R.A. Gonzalez, D.M. Tiekink, E.R.T. Walmsley, J.A. |
| author_facet |
Adrian, R.A. Gonzalez, D.M. Tiekink, E.R.T. Walmsley, J.A. |
| author_sort |
Adrian, R.A. |
| title |
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
| title_short |
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
| title_full |
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
| title_fullStr |
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
| title_full_unstemmed |
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) |
| title_sort |
tetrakis(4-cyanopyridine)palladium(ii) bis(trifluoromethanesulfonate) |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/12529/ |
| _version_ |
1643689317382488064 |