Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one

In the title β-thiocarbonyl compound, C16H16O2S, the carbonyl and methoxy O atoms are approximately coplanar [O - C - C - O torsion angle = - 18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In...

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Main Authors:	Zukerman-Schpector, J., Olivato, P.R., Traesel, H.J., Valença, J., Rodrigues, D.N.S., Tiekink, E.R.T.
Format:	Article
Published:	International Union of Crystallography 2015
Subjects:	Q Science (General) QD Chemistry
Online Access:	http://eprints.um.edu.my/19260/ http://dx.doi.org/10.1107/S205698901402550X
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Institution:	Universiti Malaya

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spelling	my.um.eprints.192602018-09-18T08:30:41Z http://eprints.um.edu.my/19260/ Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one Zukerman-Schpector, J. Olivato, P.R. Traesel, H.J. Valença, J. Rodrigues, D.N.S. Tiekink, E.R.T. Q Science (General) QD Chemistry In the title β-thiocarbonyl compound, C16H16O2S, the carbonyl and methoxy O atoms are approximately coplanar [O - C - C - O torsion angle = - 18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supramolecular chains are formed along the c axis mediated by C - H⋯O interactions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific intermolecular interactions between them. International Union of Crystallography 2015 Article PeerReviewed Zukerman-Schpector, J. and Olivato, P.R. and Traesel, H.J. and Valença, J. and Rodrigues, D.N.S. and Tiekink, E.R.T. (2015) Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one. Acta Crystallographica Section E: Crystallographic Communications, 71 (1). o3-o4. ISSN 2056-9890 http://dx.doi.org/10.1107/S205698901402550X doi:10.1107/S205698901402550X
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
topic	Q Science (General) QD Chemistry
spellingShingle	Q Science (General) QD Chemistry Zukerman-Schpector, J. Olivato, P.R. Traesel, H.J. Valença, J. Rodrigues, D.N.S. Tiekink, E.R.T. Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
description	In the title β-thiocarbonyl compound, C16H16O2S, the carbonyl and methoxy O atoms are approximately coplanar [O - C - C - O torsion angle = - 18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supramolecular chains are formed along the c axis mediated by C - H⋯O interactions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific intermolecular interactions between them.
format	Article
author	Zukerman-Schpector, J. Olivato, P.R. Traesel, H.J. Valença, J. Rodrigues, D.N.S. Tiekink, E.R.T.
author_facet	Zukerman-Schpector, J. Olivato, P.R. Traesel, H.J. Valença, J. Rodrigues, D.N.S. Tiekink, E.R.T.
author_sort	Zukerman-Schpector, J.
title	Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
title_short	Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
title_full	Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
title_fullStr	Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
title_full_unstemmed	Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
title_sort	crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one
publisher	International Union of Crystallography
publishDate	2015
url	http://eprints.um.edu.my/19260/ http://dx.doi.org/10.1107/S205698901402550X
_version_	1643690935302750208

Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one

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