Synthesis of new chiral macrocycles-based glycolipids and its application in asymmetric Michael addition

• Main Authors: Sabah, Karem J., Mat Zahid, Noor Idayu, Hashim, Rauzah
• Format: Article
• Published: Springer Verlag 2021
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/26974/
• Institution: Universiti Malaya

A series of new mix aza- and thia-macrocyclic glycolipids (9, 111, 16 and 17) have been synthesized and their enantiomeric selectivity was studied. The synthesis of the macrocycles involved a simple protection of two hydroxyl groups of the glycolipids followed by building up the mix-heteroatom macro...