Aquachloridobis(2-{ 3-(morpholin-4-yl)propyl iminomethyl}phenolato)manganese(III) monohydrate

• Main Authors: Hisham, N.A.I., Ali, Hapipah Mohd, Khaledi, H.
• Format: Article
• Language: English
• Published: International Union of Crystallography 2011
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5233/1/Hisham-2011-Aquachloridobis%282-%7B.pdf; http://eprints.um.edu.my/5233/; http://scripts.iucr.org/cgi-bin/paper?S1600536811026493
• Institution: Universiti Malaya

In the title compound, [Mn(C14H19N2O2)(2)Cl(H2O)]center dot H2O, the Mn-III atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O-H center dot center dot center dot N, O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network through C-H center dot center dot center dot O interactions.