Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II)
In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry....
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5236/1/Hisham-2011-Dichlorido%7B2-morphol.pdf http://eprints.um.edu.my/5236/ http://journals.iucr.org/e/issues/2011/01/00/pv2366/index.html http://dx.doi.org/10.1107/s1600536810050671 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C-H center dot center dot center dot Cl interaction occurs. In the crystal, adjacent molecules are linked together via C-H center dot center dot center dot Cl hydrogen-bonding and long range C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions into a three-dimensional network. |
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