Bis{mu-2-(1H-indol-3-yl)-N '- 1-(5-methyl-2-oxidophenyl)ethylidene acetohydrazidato}bis aquazinc(II ) dimethyl sulfoxide tetrasolvate
The dinuclear title compound, [Zn-2(C19H17N3O2)(2)(H2O)(2)]center dot-4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydroxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5425/1/Zuraini-2008-Bis%7Bmu-2-%281H-indol-3.pdf http://eprints.um.edu.my/5425/ http://scripts.iucr.org/cgi-bin/paper?S1600536808022034 |
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| Institution: | Universiti Malaya |
| Language: | English |
| Summary: | The dinuclear title compound, [Zn-2(C19H17N3O2)(2)(H2O)(2)]center dot-4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydroxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water molecule. Hydrogen bonds, with the water molecule serving as donor atom, lead to the formation of a linear chain motif. There is an N-H center dot center dot center dot O hydrogen bond between the complex molecule and solvent O atom. |
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