Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film
Activated carbon; Crystal structure; Crystalline materials; Crystallinity; Glass substrates; Hybrid materials; Morphology; Organometallics; Screen printing; Thin films; Zeolites; Binderless; Facile method; Fatty alcohols; MOF-199; Oil based; Property; Reduced modulus; Screen-printed; Synthesised; Th...
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Springer Science and Business Media Deutschland GmbH
2023
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my.uniten.dspace-272392023-05-29T17:41:26Z Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film Fadli M.F.M. Othman S.Z. Wai O.J. Amin N. Matsumoto A. Misran H. 57411757600 55548997100 57485940500 7102424614 14525231700 6506899840 Activated carbon; Crystal structure; Crystalline materials; Crystallinity; Glass substrates; Hybrid materials; Morphology; Organometallics; Screen printing; Thin films; Zeolites; Binderless; Facile method; Fatty alcohols; MOF-199; Oil based; Property; Reduced modulus; Screen-printed; Synthesised; Thin-films; Fabrication This paper reports on the nanohardness properties of copper-based metal-organic framework (MOF-199) synthesized in-house by facile method fabricated into bulk adsorbents by binder-less compression and into thin-film by screen-printing. 13�mm diameter bulk adsorbents were prepared for four different materials 1) MOF-199, 2) zeolite 13X, 3) activated carbon (AC) and 4) hybrid MOF-199: AC (1:1). In addition, MOF-199 was fabricated into thin-film on soda-lime glass substrates using screen-printing method. Polyvinyl acetate (PVA) was replaced with environmental-friendly binder materials of gum Arabic (gA) and palm oil based fatty alcohol (PODFA) with 8 carbon chain of decyl alcohol. X-ray diffraction (XRD) analyses of MOF-199 fabricated both by binder-less compression and screen-printing exhibited a prominent peak at ca. 2? = 11.7� attributable to (222) reflection plane of octahedral crystal structure suggesting that morphology and crystallinity were retained after fabrication processes. The octahedral morphology at ca. 1��m and ca. 2��m were observed for screen-printed thin film suggesting that the structure was preserved. Reduced modulus (R*) for pure MOF-199 and hybrid MOF-199:AC bulk adsorbents were at ca. 2.818�GPa and 0.002�GPa, respectively suggesting that hybrid adsorbent was not suitable for applications due to lack of hardness. Reduced modulus value of MOF-199 thin-film were higher at ca. 6.577�GPa (gA), 3.539�GPa (PVA), and 0.816�GPa (PODFA), respectively. � 2022, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. Final 2023-05-29T09:41:25Z 2023-05-29T09:41:25Z 2022 Conference Paper 10.1007/978-981-16-9949-8_15 2-s2.0-85126228229 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85126228229&doi=10.1007%2f978-981-16-9949-8_15&partnerID=40&md5=076e60c943b3a4a88424dd10a888bb35 https://irepository.uniten.edu.my/handle/123456789/27239 80 85 Springer Science and Business Media Deutschland GmbH Scopus |
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Activated carbon; Crystal structure; Crystalline materials; Crystallinity; Glass substrates; Hybrid materials; Morphology; Organometallics; Screen printing; Thin films; Zeolites; Binderless; Facile method; Fatty alcohols; MOF-199; Oil based; Property; Reduced modulus; Screen-printed; Synthesised; Thin-films; Fabrication |
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57411757600 |
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57411757600 Fadli M.F.M. Othman S.Z. Wai O.J. Amin N. Matsumoto A. Misran H. |
| format |
Conference Paper |
| author |
Fadli M.F.M. Othman S.Z. Wai O.J. Amin N. Matsumoto A. Misran H. |
| spellingShingle |
Fadli M.F.M. Othman S.Z. Wai O.J. Amin N. Matsumoto A. Misran H. Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| author_sort |
Fadli M.F.M. |
| title |
Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| title_short |
Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| title_full |
Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| title_fullStr |
Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| title_full_unstemmed |
Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film |
| title_sort |
nanohardness properties of mof-199 synthesized using facile method as bulk adsorbents and screen-printed thin-film |
| publisher |
Springer Science and Business Media Deutschland GmbH |
| publishDate |
2023 |
| _version_ |
1806428370851856384 |