Evaluation of palladacycles as a non-rhodium based alternative for the asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated enones

• Main Authors: Wong, Jonathan, Gan, Kennard, Chen, Houguang Jeremy, Pullarkat, Sumod A.
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2014
• 主題: DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis
• 在線閱讀: https://hdl.handle.net/10356/103735; http://hdl.handle.net/10220/24564

The asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds is an extremely versatile and widely used organic transformation. While the rhodium(I)-catalysed reaction has been thoroughly explored, the asymmetric palladium-catalysed protocol is far less developed a...