Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes
New trick for an old cat.: Triazolium-based N-heterocyclic carbenes (NHCs) catalyze the selective generation of acyl anion equivalents for the title reaction. The stereoelectronic properties of the enal-derived Breslow intermediates and the unique reactivity of the modified chalcones are crucial for...
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| Main Authors: | , , , |
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| 格式: | Article |
| 語言: | English |
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2014
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| 在線閱讀: | https://hdl.handle.net/10356/104207 http://hdl.handle.net/10220/19457 |
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