Stereogenic lock in 1-naphthylethanamine complexes for catalyst and auxiliary design : structural and reactivity analysis for cycloiridated pseudotetrahedral complexes

• المؤلفون الرئيسيون: Chen, Jeremy Houguang, Teo, Ronald Hong Xiang, Li, Yongxin, Pullarkat, Sumod Appukuttan, Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2019
• الموضوعات: Science::Chemistry::Biochemistry; Stereogenic; Cycloiridated Complex
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/104477; http://hdl.handle.net/10220/49996
• المؤسسة: Nanyang Technological University

A series of optically active pseudo-tetrahedral five-membered cyclometalated 1-naphthylethanamine iridium(III) complexes were prepared and characterized to analyze the efficacy of the stereogenic conformational lock in both solid and solution phases. The synthesis of the iridacycles was diastereosel...