Chiral nitroarenes as enantioselective single-electron-transfer oxidants for carbene-catalyzed radical reactions
A new class of chiral oxidants is developed. These readily accessible oxidants contain a nitro group for oxidation and a chiral sulfonamide moiety for stereoselectivity control. The chiral information from the oxidants can effectively transfer to the substrates in carbene-catalyzed β-hydroxylation o...
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Main Authors: | , , , , , , , |
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格式: | Article |
語言: | English |
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2020
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在線閱讀: | https://hdl.handle.net/10356/137777 |
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機構: | Nanyang Technological University |
語言: | English |