Addition of N-heterocyclic carbene catalyst to aryl esters induces remote C-Si bond activation and benzylic carbon functionalization
Through the incorporation of a silicon atom to an aryl carboxylic ester substrate, the resulting C-Si bond can be activated via the addition of a carbene catalyst on a remote site. This strategy allows for efficient functionalization of the benzylic sp3-carbons of aryl carboxylic esters.
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Main Authors: | Wang, Hongling, Chen, Xingkuan, Li, Yongjia, Wang, Jilan, Wu, Shuquan, Xue, Wei, Yang, Song, Chi, Robin Yonggui |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/138275 |
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Institution: | Nanyang Technological University |
Language: | English |
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