Organocatalyzed living radical polymerization of itaconates and self-assemblies of rod-coil block copolymers

• المؤلفون الرئيسيون: Hu, Keling, Sarkar, Jit, Zheng, Jie, Lim, Melania Yan Hui, Goto, Atsushi
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Block Copolymers; Itaconates
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/142518
• المؤسسة: Nanyang Technological University

Organocatalyzed living radical polymerizations of itaconates are studied, yielding low-dispersity linear and star polymers (Đ = Mw /Mn = 1.28-1.46) up to Mn = 20 000 and monomer conversion = 62%, where Mn and Mw are the number- and weight-average molar masses, respectively. The block polymerization...