Platinum-osmium heterometallic clusters containing N-heterocyclic carbene ligands and an electron-deficient tetraosmium by-product
The room temperature reaction of [Os 3 (CO) 12 ] (1) with three molar equivalents of [PtCl(allyl)(NHC)] (2) in the presence of KOtBu afforded the heterometallic clusters [PtOs 3 (CO) 12 (NHC)] (3), [Pt 2 Os 3 (CO) 12 (NHC) 2 ] (4), and [Pt 3 Os 3 (CO) 12 (NHC) 3 ] (5), together with a trace amount o...
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| Main Authors: | , , , |
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| 格式: | Article |
| 語言: | English |
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2020
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| 在線閱讀: | https://hdl.handle.net/10356/142976 |
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