Synthesis and properties of phospha[5]helicenes bearing an inner-rim phosphorus center

• المؤلفون الرئيسيون: Md. Shafiqur Rahman, Yoshikai, Naohiko
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Chirality; Oxides
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/143717
• المؤسسة: Nanyang Technological University

New phospha[5]helicene derivatives featuring angular fusion of phosphole and carbohelicene moieties have been synthesized using 7-hydroxybenzo[b]phosphole oxide as a key intermediate, which can be regioselectively prepared through one-pot multicomponent coupling. The structural behavior of the prese...