Synthesis of vinyl iodide chain-end polymers via organocatalyzed chain-end transformation

• المؤلفون الرئيسيون: Chang, Jun Jie, Pan, Matthew Houwen, Goto, Atsushi
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry::Organic chemistry::Polymers; Vinyl Iodide Chain-end Polymers; Polymer Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/147423

In the presence of alkynes (CH≡C–R2), iodide chain-end polymers (Polymer–I) were successfully transformed to vinyl iodide chain-end polymers (Polymer–CH=CR2–I) in a single step via organocatalysis. This reaction is completely metal-free and easy to carry out without using special reagents or special...