Isomers in the phosphine-substituted heteronuclear cluster RuOs(µ-H)₂(CO)₁₂(PPh₃) – a re-examination

• المؤلفون الرئيسيون: Ng, Shi Hoe, Leong, Weng Kee
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry; Osmium; Ruthenium
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/154509

The solution-state isomers of the heteronuclear cluster RuOs3(µ-H)2(CO)12(PPh3) have been re-examined in the light of conflicting structural assignments for a closely-related analogue. The result is a reassignment of the structures and hence the exchange processes observed in the NMR spectra.