Catalyst control over S(IV)-stereogenicity via carbene-derived sulfinyl azolium intermediates

• Main Authors: Li, Benpeng, Hu, Junyuan, Liao, Minghong, Xiong, Qin, Zhang, Yaqi, Chi, Robin Yonggui, Zhang, Xinglong, Wu, Xingxing
• 其他作者: School of Chemistry, Chemical Engineering and Biotechnology
• 格式: Article
• 語言: English
• 出版: 2025
• 主題: Chemistry; Catalysts; Sulfur-stereogenic compounds
• 在線閱讀: https://hdl.handle.net/10356/183587
• 機構: Nanyang Technological University

Stereoselective synthesis utilizing small-molecule catalysts, particularly N-heterocyclic carbene (NHC), has facilitated swift access to enantioenriched molecules through diverse activation modes and NHC-bound reactive intermediates. While carbonyl derivatives, imines, and "activated" alke...