Asymmetric synthesis of chiral arsines and phosphines and their stability investigation

• Main Author: Ma, Meng Tao
• Other Authors: Leung Pak Hing
• Format: Theses and Dissertations
• Language: English
• Published: 2009
• Subjects: DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis
• Online Access: https://hdl.handle.net/10356/19295
• Institution: Nanyang Technological University

The organopalladium complex containing ortho-metalated (S)-[1-(dimethylamino)ethyl]naphthalene (+)-41 as the chiral auxiliary has been successfully used as the chiral template to promote the asymmetric cycloaddition reactions between 3,4-dimethyl-1-phenylarsole (DMPA) and several kinds of vinylphosp...