Text this: Part I: synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. Part II: Synthesis of 3,4-2H-dihydropyrroles starting from alkenyl carbonitriles and grignard reagents via Cu(II)-mediated iminooxygenation of N-H imines with tempo

  _____    __   __              ______   ______   
 /  ___||  \ \\/ //   ____     /_   _// |      \\ 
| // __     \ ` //   |    \\    -| ||-  |  --  // 
| \\_\ ||    | ||    | [] ||    _| ||_  |  --  \\ 
 \____//     |_||    |  __//   /_____// |______// 
  `---`      `-`'    |_|`-`    `-----`  `------`  
                     `-`