Ruthenium-based structural mimics of [Fe]-hydrogenase

• المؤلف الرئيسي: Barik, Chandan Kr
• مؤلفون آخرون: Leong Weng Kee
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2018
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/73456
• المؤسسة: Nanyang Technological University

In this thesis, a series of group VIII metal complexes which are structural mimics of the [Fe]-hydrogenase active site were examined. These were monodentate thiolato complexes of formulae [Ru(2-NHC(O)C5H3NMe)(CO)2(o,o-Me2C6H3S)(L)] (L = MeCN or PMe3), and N,S-bidentate mercaptopyridine complexes of...