Synthesis of allahabadolactone A

• المؤلفون الرئيسيون: Wang, Kongchen, Bates, Roderick Wayland
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2019
• الموضوعات: DRNTU::Science::Chemistry; Allahabadolactone; Hydrogen Peroxide
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/88952; http://hdl.handle.net/10220/48340
• المؤسسة: Nanyang Technological University

A synthesis of allahabadolactone A is described employing diastereoselective Diels–Alder and selenocyclization reactions, starting from (R)-citronellal and propylene oxide. The Diels–Alder substrate is built up in an efficient manner by rhodium-catalyzed alkyne hydroboration and palladium-catalyzed...