Ethylene insertion in the presence of new alkoxysilane electron donors for Ziegler-Natta catalyzed polyethylene

• Main Authors: Kruawan S., Ratanasak M., Chanajaree R., Rungrotmongkol T., Saengsawang O., Parasuk V., Kungwan N., Hannongbua S.
• 格式: 雜誌
• 出版: 2017
• 在線閱讀: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85018624812&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/40269

© 2017 Density functional theory (DFT) calculations have been carried out to investigate the ethylene insertion pathway using a Ziegler-Natta catalyst in the absence and presence of electron donor (ED) systems on the (1 1 0) MgCl 2 surface. The coadsorptions of four different EDs i.e. Si(OEt) m Cl...