Orthorhombic Molybdenum Trioxide Whiskers by Vapor Transport Method

Orthorhombic MoO3 whiskers have been grown by using vapor transport method. High-quality, transparent and colorless MoO3 plate-like whiskers are obtained inside alumina furnace tube with high aspect ratio of 20-30 for the growth time of 1 h. The length and the width of whiskers are directly proporti...

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Main Authors: Choopun S., Mangkorntong P., Subjareon P., Mangkorntong N., Tabata H., Kawai T.
格式: Article
語言:English
出版: 2014
在線閱讀:http://www.scopus.com/inward/record.url?eid=2-s2.0-1842708966&partnerID=40&md5=10eedfc8603202c015a965a3323608f0
http://cmuir.cmu.ac.th/handle/6653943832/4796
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總結:Orthorhombic MoO3 whiskers have been grown by using vapor transport method. High-quality, transparent and colorless MoO3 plate-like whiskers are obtained inside alumina furnace tube with high aspect ratio of 20-30 for the growth time of 1 h. The length and the width of whiskers are directly proportional to growth time. The location that whiskers occurred is an evidence of vapor-solid growth mechanism by sublimation. From characterization, MoO3 whiskers exhibit a near-perfect single crystal with high purity of orthorhombic phase, smooth morphology, and indirect band gap of 2.98 eV. MoO3 whisker has also been demonstrated as a gas sensor toward ethanol vapor.