Ruthenocenyl ruthenium bimetallic complexes: Electrospray mass spectrometric study of [RuX(η5-C5H5)(η2-dppr)] n+ (dppr=1,1′-bis(diphenylphosphino)ruthenocene) (X=Cl, n=0; X=CO, CH3...

by Po Yeo, S., Henderson, W., Mak, T.C.W., Hor, T.S.A.
Published 2014

Nitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)

by Neo, S.-P., Hor, T.S.A., Zhou, Z.-Y., Mak, T.C.W.
Published 2014

Promotion of tetrahedral copper(I) dimers by chelation of 1,1′-bis(diphenylphosphino)ferrocene (dppf). Crystal structures of [{Cu(μ-X)(dppf-P,P′)}2](X = O2CH, I or NO3)

by Neo, S.P., Zhou, Z., Mak, T.C.W., Hor, T.S.A.
Published 2014

Solid-state tetramer vs solution-state dimer. Reinvestigation of [Ag2(OAc)2(dppm)]2 and its dppm addition product [Ag(OAc)(dppm)]2 (dppm = Ph2PCH2PPh2)

by Neo, S.P., Zhou, Z.-Y., Mak, T.C.W., Hor, T.S.A.
Published 2014

1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2

by Lai-Tee, P., Hor, T.S.A., Zhong-Yuan, Z., Mak, T.C.W.
Published 2014

Gracilipene: A heterocyclic seco-trisnor-oleanane from Calophyllum gracilipes (Guttiferae)

by Cao, S.-G., Sim, K.-Y., Goh, S.-H., Xue, F., Mak, T.C.W.
Published 2014

General synthesis of ferrocenylphosphine-bridged digold carboxylato complexes: Crystal and molecular structure of Au2(η1-CF3CO2) 2(μ-dppf) · C6H14 (dppf = Fe(C5H4PPh2)2)

by Low, P.M.N., Zhang, Z.-Y., Mak, T.C.W., Hor, T.S.A.
Published 2014

Molecular structures of 1,1′bis(diphenylphosphino) ferrocene oxide and sulphide and their thermal properties

by Fang, Z.-G., Andy, T.S., Wen, Y.-S., Liu, L.-K., Mak, T.C.W.
Published 2014

Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2C...

by Li, G., Lam, C.-K., Chien, S.W., Mak, T.C.W., Andy Hor, T.S.
Published 2014

Heteropolymetallic aggregates from [Pd2(dppf)2(μ-S)2]. Bonding and structural analysis of [Ag2Pd2Cl2(dppf)2(μ 3-S)2]·4CH2Cl2 [dppf = Fe(C5H4PPh2)2] - A flat {Pd2S2} core with two A...

by Li, G., Li, S., Tan, A.L., Yip, W.-H., Mak, T.C.W., Hor, T.S.A.
Published 2014

Catalytic and stoichiometrically directed synthesis of less accessible bromothiophenes and bromobithiophenes. Trapping and characterization of catalytic intermediates of trans-PdBr...

by Xie, Y., Wu, B.-M., Xue, F., Ng, S.-C., Mak, T.C.W., Andy Hor, T.S.
Published 2014

σ-Thienyl complexes of palladium(II), trans-PdBr(C4H4-nBrn-1S-C)(PPh3)2(n = 1-4), from oxidative addition of bromothiophenes to Pd(PPh3)4. X-ray structural identification of key in...

by Xie, Y., Ng, S.C., Wu, B.-M., Xue, F., Mak, T.C.W., Hor, T.S.A.
Published 2014

Ferrocenyl phosphine mobility, positional isomerism and NMR fluxionality in triangular palladium sulfide aggregates. Crystal and molecular structures of [Pd3Cl2(η2-dppf)(μ-dppf)(μ...

by Yeo, J.S.L., Li, G., Yip, W.-H., Henderson, W., Mak, T.C.W., Hor, T.S.A.
Published 2014

Co-ordination and catalytic chemistry of 1,1′-bis(diphenylphosphino)-ruthenocene (dppr). Synthesis of [MCl2(dppr)] (M = Ni, Pd or Pt) and molecular structures of dppr and [PtCl2(dp...

by Li, S., Wei, B., Low, P.M.N., Lee, H.K., Hor, T.S.A., Xue, F., Mak, T.C.W.
Published 2014

Metal-metal cooperation via 1,1′-bis(diphenylphosphino)ferrocene (dppf). 1. Structurally distinctive silver(I) dppf complexes of nitrato and carboxylato ligands in variable coordin...

by Hor, T.S.A., Neo, S.P., Tan, C.S., Mak, T.C.W., Leung, K.W.P., Wang, R.-J.
Published 2014

Substituted metal carbonyls. Part 21. [M(CO)5(dppf-P)] [M = Cr, Mo or W; Dppf = Fe(C5H4PPh2)2] as a metalloligand in heteropolymetallic aggregates of AuI, PdII and PtII. Crystal an...

by Phang, L.-T., Au-Yeung, S.C.F., Hor, T.S.A., Khoo, S.B., Zhou, Z.-Y., Mak, T.C.W.
Published 2014

From aggregates to clusters. Facile formation of hetero-metal-metal bonds through reductive desulfurization by CO in a decapacitative transformation of a {Pt2MS2} Tbp frame to a {P...

by Liu, H., Tan, A.L., Mok, K.F., Mak, T.C.W., Batsanov, A.S., Howard, J.A.K., Andy Hor, T.S.
Published 2014

Bis(carboxylato) complexes of platinum(II). Structural and bonding analysis of [Pt(O2CR)2(L-L)] [L-L = 2PPh3, Ph2PCH2PPh2 or Fe(C5H4PPh2)2; R = Me, CF3, Pri or Ph]

by Tan, A.L., Low, P.M.N., Zhou, Z.-Y., Zheng, W., Wu, B.-M., Mak, T.C.W., Hor, T.S.A.
Published 2014

Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)

by Neo, Y.C., Yeo, J.S.L., Low, P.M.N., Chien, S.W., Mak, T.C.W., Vittal, J.J., Hor, T.S.A.
Published 2014