The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate
Application of polymer science for alternative energy discovery have been developed recently. Along side with the increase of energy demand, discovery of this new alternative energy is very promising and enviromentally friendly. One of fuel cell, Proton Exchange Membrane Fuel Cell (PEMFC) use polyme...
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id-itb.:125692017-09-27T11:42:36ZThe Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate RAKHMA HUSEIN (NIM 10505040), RIFTI Indonesia Final Project INSTITUT TEKNOLOGI BANDUNG https://digilib.itb.ac.id/gdl/view/12569 Application of polymer science for alternative energy discovery have been developed recently. Along side with the increase of energy demand, discovery of this new alternative energy is very promising and enviromentally friendly. One of fuel cell, Proton Exchange Membrane Fuel Cell (PEMFC) use polymer as electrolyte membrane. This membrane is use as proton transfer media. In this research, polyblend of sulfonated polystyrene (PSS)-lignosulfonate (LS) are added divynil benzene (DVB) in order to synthesis the membrane. Polystyrene was sulfonated in order to have –SO3H group which has the ability to transfer proton. The using of LS is to increase the mechanical strength and the conductivity of membrane, and the addition of DVB expected to increase the mechanical stability. Polyblend was synthesized with various amount of DVB (2%, 4%, 6% and 8% (w/w)), whereas the amount of the LS used ini this polyblend preparation is constant (5%(w/w)). This membrane are characterized by Fourier Transform Infra Red (FTIR), swelling, Ion Exchange Capacity (KPI), conductivity, mechanical analysis, TGA/DTA, and XRD. Results show that the increase amount of DVB on polyblend of PSS-LS, swelling degree and mechanical strength are decreased while, the results of thermal stability and KPI are not changed significantly. text |
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Application of polymer science for alternative energy discovery have been developed recently. Along side with the increase of energy demand, discovery of this new alternative energy is very promising and enviromentally friendly. One of fuel cell, Proton Exchange Membrane Fuel Cell (PEMFC) use polymer as electrolyte membrane. This membrane is use as proton transfer media. In this research, polyblend of sulfonated polystyrene (PSS)-lignosulfonate (LS) are added divynil benzene (DVB) in order to synthesis the membrane. Polystyrene was sulfonated in order to have –SO3H group which has the ability to transfer proton. The using of LS is to increase the mechanical strength and the conductivity of membrane, and the addition of DVB expected to increase the mechanical stability. Polyblend was synthesized with various amount of DVB (2%, 4%, 6% and 8% (w/w)), whereas the amount of the LS used ini this polyblend preparation is constant (5%(w/w)). This membrane are characterized by Fourier Transform Infra Red (FTIR), swelling, Ion Exchange Capacity (KPI), conductivity, mechanical analysis, TGA/DTA, and XRD. Results show that the increase amount of DVB on polyblend of PSS-LS, swelling degree and mechanical strength are decreased while, the results of thermal stability and KPI are not changed significantly. |
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Final Project |
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RAKHMA HUSEIN (NIM 10505040), RIFTI |
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RAKHMA HUSEIN (NIM 10505040), RIFTI The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
author_facet |
RAKHMA HUSEIN (NIM 10505040), RIFTI |
author_sort |
RAKHMA HUSEIN (NIM 10505040), RIFTI |
title |
The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
title_short |
The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
title_full |
The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
title_fullStr |
The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
title_full_unstemmed |
The Effect of Divinyl Benzene in Polystyrene Characteristics and Its Polyblend with Lignosulfonate |
title_sort |
effect of divinyl benzene in polystyrene characteristics and its polyblend with lignosulfonate |
url |
https://digilib.itb.ac.id/gdl/view/12569 |
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1820728559552954368 |