STUDY OF METAL MOBILITY IN LABORATORY SCALE FDCLT KINETIC TEST OF LOW SULPHIDATION EPITHERMAL ROCK SAMPLES

Mine water is one of the negative impacts arising from mining activities. Acidic mine water is dominated by sulfates as a result of the reaction of sulfide minerals in rocks exposed to water and oxygen. Additionally, the acidity of mine water characterized by the increased dissolved metals, inclu...

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Bibliographic Details
Main Author: Kadji, Robertho
Format: Theses
Language:Indonesia
Online Access:https://digilib.itb.ac.id/gdl/view/71191
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Institution: Institut Teknologi Bandung
Language: Indonesia
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Summary:Mine water is one of the negative impacts arising from mining activities. Acidic mine water is dominated by sulfates as a result of the reaction of sulfide minerals in rocks exposed to water and oxygen. Additionally, the acidity of mine water characterized by the increased dissolved metals, including trace elements, compared to water from natural systems. Variations in the geochemical characteristics of mine water and the possibility of associated metal mobility are dependent on the interaction of water and rock, so predictions and modeling are necessary to minimize the impact on the surrounding environment. The purpose of this study was to determine the potential for the formation of acid mine drainage as well as the mobility of metals and the characteristics of leach water from rocks in Low Sulfidation Epithermal (LSE) deposits. The rock samples from the LSE deposits were characterized geochemically for the formation of Acid Mine Water (AAT) using static tests, mineralogical tests and elements, as well as kinetic testing using the free draining column leach test (FDCLT) method. The leachate resulting from the kinetic test was tested to determine the physicochemical properties of the leachate. LSE rock samples were also subjected to seguential extraction and near total acid digestion tests to calculate the amount and relative mobility of metals in various geochemical Jractions. The results showed that rock samples in the same lithology had different geochemical characteristics of AAT formation, thus affecting the physicochemical conditions of the leachate resulting from the interaction of water and rocks. There were 7 samples producing circumneutral leachates and 2 samples with acidic leachates. Metal mobility in LSE deposits has various characteristics. In general, metals are bound to the carbonate fraction. The availability and mobility of mobile metals in the soluble and carbonate fractions as sources of pollutants in the environment will depend on the physicochemical conditions of the leachate formed. Rocks that have metal mobility in the carbonate fraction can be readily dissolved if there is interaction with acidic leachates from other rocks.