STEREOSELECTIVE ISOMERIZATION OF EUGENOL TO TRANS-ISOEUGENOL CATALYZED BY IN SITU GENERATED NICKEL(0) PHOSPHINES

Double bond isomerization of eugenol to only trans-isoeugenol was successfully catalyzed by in situ generated Ni(0) phosphine from inexpensive Ni(II) sources (NiCl2(PPh3)2, NiCl2?6H2O, Ni(NO3)2?6H2O, or Ni(OAc)2?4H2O), phosphine ligands (PPh3, P(Ph-pOMe)3, or P(Ph-pMe)3), and reducing agent Zn. H...

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Bibliographic Details
Main Author: Saputra, Leo
Format: Theses
Language:Indonesia
Subjects:
Online Access:https://digilib.itb.ac.id/gdl/view/71440
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Institution: Institut Teknologi Bandung
Language: Indonesia