PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)

The Effect of Alkyl Group in Acetyl Chloride and Butanoyl Chloride on The Percentage of Ferulic Acid Esterification (Using Microwave Irradiation) Frida Putri Nur Islami 4-acetoxy-3-methoxycinnamic acid was synthesized by reacting ferulic acid and acetyl chloride whereas 4-butoxy-3-methoxycinnam...

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Main Author:	FRIDA PUTRI NUR ISLAMI, 051211131073
Format:	Theses and Dissertations NonPeerReviewed
Language:	Indonesian Indonesian
Published:	2016
Subjects:	RS1-441 Pharmacy and materia medica
Online Access:	http://repository.unair.ac.id/56146/1/FF.%20KF.%2022%20-16%20Isl%20p%20abstrak.pdf http://repository.unair.ac.id/56146/2/FF.%20KF.%2022%20-16%20Isl%20p.pdf http://repository.unair.ac.id/56146/ http://lib.unair.ac.id
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Institution:	Universitas Airlangga
Language:	Indonesian Indonesian

id	id-langga.56146
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spelling	id-langga.561462017-04-09T16:36:52Z http://repository.unair.ac.id/56146/ PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro) FRIDA PUTRI NUR ISLAMI, 051211131073 RS1-441 Pharmacy and materia medica The Effect of Alkyl Group in Acetyl Chloride and Butanoyl Chloride on The Percentage of Ferulic Acid Esterification (Using Microwave Irradiation) Frida Putri Nur Islami 4-acetoxy-3-methoxycinnamic acid was synthesized by reacting ferulic acid and acetyl chloride whereas 4-butoxy-3-methoxycinnamic acid was made from the reaction of ferulic acid and butanoyl chloride. This synthesis was carried through the substitution mechanism of nucleophilic acyl using microwave irradiation. The Optimum percentage in the synthesis of 4-acetoxy-3-methoxycinnamic acid was observed at 40 watt and 0,5 min. In order to study the effect of alkyl group length to the percentage of ferulic acid esterification, acetyl chloride and butanoyl chloride were used as acyl halides in this research. The result show that the length of alkyl group in acetyl chloride and butanoyl chloride has no effect toward the percentage of ferulic acid esterification. The characterization of 4-acetoxy-3-methoxycinnamic acid and 4-butoxy-3-methoxy cinnamic acid was performed using melting point test, UV-Vis spectrophotometry, FT-IR spectrophotometry, 1H-NMR spectrometry. The synthetic percentage of 4-acetoxy-3-methoxycinnamic acid and 4-butoxy-3-methoxy cinnamic acid were found to be 95,04 % ± 1,70 and 66,37 % ± 4,34, respectively. Both of them show the optimum reaction at 40 watt and 0,5 min. Keyword : 4-acetoxy-3-methoxycinnamic acid, 4-butoxy-3- methoxycinnamic acid, microwave irradiation, acetyl chloride, butanoyl chloride 2016 Thesis NonPeerReviewed text id http://repository.unair.ac.id/56146/1/FF.%20KF.%2022%20-16%20Isl%20p%20abstrak.pdf text id http://repository.unair.ac.id/56146/2/FF.%20KF.%2022%20-16%20Isl%20p.pdf FRIDA PUTRI NUR ISLAMI, 051211131073 (2016) PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro). Skripsi thesis, Universitas Airlangga. http://lib.unair.ac.id
institution	Universitas Airlangga
building	Universitas Airlangga Library
country	Indonesia
collection	UNAIR Repository
language	Indonesian Indonesian
topic	RS1-441 Pharmacy and materia medica
spellingShingle	RS1-441 Pharmacy and materia medica FRIDA PUTRI NUR ISLAMI, 051211131073 PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
description	The Effect of Alkyl Group in Acetyl Chloride and Butanoyl Chloride on The Percentage of Ferulic Acid Esterification (Using Microwave Irradiation) Frida Putri Nur Islami 4-acetoxy-3-methoxycinnamic acid was synthesized by reacting ferulic acid and acetyl chloride whereas 4-butoxy-3-methoxycinnamic acid was made from the reaction of ferulic acid and butanoyl chloride. This synthesis was carried through the substitution mechanism of nucleophilic acyl using microwave irradiation. The Optimum percentage in the synthesis of 4-acetoxy-3-methoxycinnamic acid was observed at 40 watt and 0,5 min. In order to study the effect of alkyl group length to the percentage of ferulic acid esterification, acetyl chloride and butanoyl chloride were used as acyl halides in this research. The result show that the length of alkyl group in acetyl chloride and butanoyl chloride has no effect toward the percentage of ferulic acid esterification. The characterization of 4-acetoxy-3-methoxycinnamic acid and 4-butoxy-3-methoxy cinnamic acid was performed using melting point test, UV-Vis spectrophotometry, FT-IR spectrophotometry, 1H-NMR spectrometry. The synthetic percentage of 4-acetoxy-3-methoxycinnamic acid and 4-butoxy-3-methoxy cinnamic acid were found to be 95,04 % ± 1,70 and 66,37 % ± 4,34, respectively. Both of them show the optimum reaction at 40 watt and 0,5 min. Keyword : 4-acetoxy-3-methoxycinnamic acid, 4-butoxy-3- methoxycinnamic acid, microwave irradiation, acetyl chloride, butanoyl chloride
format	Theses and Dissertations NonPeerReviewed
author	FRIDA PUTRI NUR ISLAMI, 051211131073
author_facet	FRIDA PUTRI NUR ISLAMI, 051211131073
author_sort	FRIDA PUTRI NUR ISLAMI, 051211131073
title	PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
title_short	PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
title_full	PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
title_fullStr	PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
title_full_unstemmed	PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)
title_sort	pengaruh gugus alkil pada asetil klorida dan butanoil klorida terhadap persentase hasil esterifikasi asam ferulat (menggunakan iradiasi gelombang mikro)
publishDate	2016
url	http://repository.unair.ac.id/56146/1/FF.%20KF.%2022%20-16%20Isl%20p%20abstrak.pdf http://repository.unair.ac.id/56146/2/FF.%20KF.%2022%20-16%20Isl%20p.pdf http://repository.unair.ac.id/56146/ http://lib.unair.ac.id
_version_	1681147353084461056

PENGARUH GUGUS ALKIL PADA ASETIL KLORIDA DAN BUTANOIL KLORIDA TERHADAP PERSENTASE HASIL ESTERIFIKASI ASAM FERULAT (Menggunakan Iradiasi Gelombang Mikro)

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