SINTESIS DAN KARAKTERISASI POLIURETAN BERPORI DARI GLISEROL DAN ETILENADIAMINA SERTA UJI KAPASITAS ADSORPSINYA TERHADAP SENYAWA KARSINOGENIK PADA ASAP ROKOK
Synthesis and characterization of porous polyurethane from glycerol and ethylenediamine with its adsorption capacity toward carcinogenic compounds on cigarette smoke was conducted. Porous polyurethane was synthesized by variations volume of glycerol toward polyethylene glycol (PEG) 1000 and 4,4'...
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| Main Authors: | , |
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| Format: | Theses and Dissertations NonPeerReviewed |
| Published: |
[Yogyakarta] : Universitas Gadjah Mada
2014
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| Subjects: | |
| Online Access: | https://repository.ugm.ac.id/133150/ http://etd.ugm.ac.id/index.php?mod=penelitian_detail&sub=PenelitianDetail&act=view&typ=html&buku_id=73707 |
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| Institution: | Universitas Gadjah Mada |
| Summary: | Synthesis and characterization of porous polyurethane from glycerol and
ethylenediamine with its adsorption capacity toward carcinogenic compounds on
cigarette smoke was conducted. Porous polyurethane was synthesized by
variations volume of glycerol toward polyethylene glycol (PEG) 1000 and 4,4'-
diphenylmethane diisocyanate (MDI). The volume ratio of glycerol toward (PEG
1000 and MDI) was 0/3, 1/3, 2/3, 3/3, and 4/3. Polyurethane with an optimum
ratio of glycerol was added ethylenediamine with some variations. Dried at 50 °C
for 3 hours. Polyurethane was characterized by FT-IR, HBI testing, swelling
degree calculating, determining of specific surface area, average pore radii, and
total pore volume with GSA, and tested resistance to solvents and adsorption
capacity of the adsorbent with smoke flowing. Furthermore, the adsorbent with
carcinogenic compound was analyzed by FT-IR and it was extracted with
dichloromethane. The extract was analyzed by GC-MS.
The results of FT-IR analysis showed that the porous polyurethane with
the addition of glycerol and ethylenediamine can be performed. Based on the HBI
and swelling degrees calculation, the optimum condition of polyurethane which
was the ratio 1/3 (PU1). The addition of ethylenediamine which produced the
character foam was added 0.05 mL (PU1E1). Under the GSA, PU1 and PU1E1
have isotherm adsorption type I (microporous) with specific surface area, average
pore radii, and total pore volume sequentially, PU1 was 17.128 m2/g |
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