Copper(i) complexes: intramolecular and intermolecular arene-c– h···π(quasi-chelate ring) interactions

• Main Authors: Yeo, Chien Ing *, Zukerman-Schpector, Julio, Ferreira, M. A. B, Tiekink, Edward R. T. *
• Format: Conference or Workshop Item
• Language: English
• Published: 2017
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/607/1/YEO%20CI%20-%20COPPER%20COMPLEXES%20INTRAMOLECULAR%20AND%20INTERMOLECULAR.pdf; http://eprints.sunway.edu.my/607/
• Institution: Sunway University

A series of bis(phosphane)copper(I) thiocarbamates, namely (Ph3P)2Cu[ROC(=S)N(H)Ph]Cl, were prepared in response to the promising biological properties exhibited by the related phosphanegold(I) analogues. The presence of an intramolecular N-H···Cl hydrogen bond in the title compounds, was found l...