2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate

The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and...

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Main Authors: Gao, S., Qi, Xiao-Juan, Kong, Li-Li, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
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Online Access:http://eprints.um.edu.my/11703/
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spelling my.um.eprints.117032019-01-31T04:08:53Z http://eprints.um.edu.my/11703/ 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. Q Science (General) The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Gao, S. and Qi, Xiao-Juan and Kong, Li-Li and Ng, S.W. (2010) 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (12). O3300-U1823. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Gao, S.
Qi, Xiao-Juan
Kong, Li-Li
Ng, S.W.
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
description The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network.
format Article
author Gao, S.
Qi, Xiao-Juan
Kong, Li-Li
Ng, S.W.
author_facet Gao, S.
Qi, Xiao-Juan
Kong, Li-Li
Ng, S.W.
author_sort Gao, S.
title 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
title_short 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
title_full 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
title_fullStr 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
title_full_unstemmed 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
title_sort 2,2 `-[p-phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/11703/
_version_ 1643689120081379328