Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur...

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Main Authors: Suleiman G, N., Ikmal H, N.A., Khaledi, H., Mohd A, H.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
R Medicine
Online Access:http://eprints.um.edu.my/1184/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050266/
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spelling my.um.eprints.11842019-01-31T02:04:04Z http://eprints.um.edu.my/1184/ Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II). Suleiman G, N. Ikmal H, N.A. Khaledi, H. Mohd A, H. QD Chemistry R Medicine In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane. International Union of Crystallography 2010 Article PeerReviewed Suleiman G, N. and Ikmal H, N.A. and Khaledi, H. and Mohd A, H. (2010) Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m108. ISSN 1600-5368 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050266/ 21522521
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
R Medicine
spellingShingle QD Chemistry
R Medicine
Suleiman G, N.
Ikmal H, N.A.
Khaledi, H.
Mohd A, H.
Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
description In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac plane.
format Article
author Suleiman G, N.
Ikmal H, N.A.
Khaledi, H.
Mohd A, H.
author_facet Suleiman G, N.
Ikmal H, N.A.
Khaledi, H.
Mohd A, H.
author_sort Suleiman G, N.
title Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
title_short Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
title_full Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
title_fullStr Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
title_full_unstemmed Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
title_sort aqua-{2-morpholino-n-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κn,n',n''}bis-(thio-cyanato-κn)nickel(ii).
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/1184/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050266/
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