An unprecedented 2-D CuSCN coordination network containing both regular and irregular [Cu3(SCN)3] rings supported by a tridentate N-donor ligand

An unprecedented 2-D CuSCN coordination network containing both regular and irregular [Cu3(SCN)3] rings supported by a tridentate N-donor ligand

A neutral 2-D (CuSCN)∞ containing both regular and irregular [Cu3(SCN)3] six-membered rings supported by an asymmetrical tridentate ligand 3,5-bis(3-pyridyl)-1H-pyrazole (Hbppz) were prepared with the formula [Cu3(SCN)3(Hbppz)] ∞. The compound gives strong green luminescence with an emission maximum...

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Bibliographic Details
Main Authors: Zhan, Shun-Ze, Peng, Rong, Lin, Shi Hong, Ng, Seik Weng, Li, Dan
Format: Article
Published: Royal Society of Chemistry 2010
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/11982/
https://doi.org/10.1039/B921264G
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Institution: Universiti Malaya
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Summary:A neutral 2-D (CuSCN)∞ containing both regular and irregular [Cu3(SCN)3] six-membered rings supported by an asymmetrical tridentate ligand 3,5-bis(3-pyridyl)-1H-pyrazole (Hbppz) were prepared with the formula [Cu3(SCN)3(Hbppz)] ∞. The compound gives strong green luminescence with an emission maximum at 536 nm. © 2010 The Royal Society of Chemistry.

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