(mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)

(mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)

In the title salt, [Zn-2(C2H8N2)(5)](ClO4)(4), an ethylenediamine molecule bridges two bis(ethylenediamine) zinc units; the five-coordinate Zn atoms show a trigonal-bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the o...

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Main Authors: Ding, Man-Hua, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/11987/
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spelling my.um.eprints.119872019-01-31T01:53:38Z http://eprints.um.edu.my/11987/ (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate) Ding, Man-Hua Ng, S.W. Q Science (General) In the title salt, [Zn-2(C2H8N2)(5)](ClO4)(4), an ethylenediamine molecule bridges two bis(ethylenediamine) zinc units; the five-coordinate Zn atoms show a trigonal-bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation interacts weakly with the anion by N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Ding, Man-Hua and Ng, S.W. (2010) (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate). Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1356-U206. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Ding, Man-Hua
Ng, S.W.
(mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
description In the title salt, [Zn-2(C2H8N2)(5)](ClO4)(4), an ethylenediamine molecule bridges two bis(ethylenediamine) zinc units; the five-coordinate Zn atoms show a trigonal-bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation interacts weakly with the anion by N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network.
format Article
author Ding, Man-Hua
Ng, S.W.
author_facet Ding, Man-Hua
Ng, S.W.
author_sort Ding, Man-Hua
title (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
title_short (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
title_full (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
title_fullStr (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
title_full_unstemmed (mu-Ethane-1,2-diamine-kappa N-2:N `)bis[bis(ethane-1,2-diamine-kappa N-2,N `)zinc(II)] tetrakis(perchlorate)
title_sort (mu-ethane-1,2-diamine-kappa n-2:n `)bis[bis(ethane-1,2-diamine-kappa n-2,n `)zinc(ii)] tetrakis(perchlorate)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/11987/
_version_ 1643689190117867520

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