Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate

Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate

In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H...

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Main Authors: Halim, S.N.A., Ali, H.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/11989/
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spelling my.um.eprints.119892019-01-29T09:11:26Z http://eprints.um.edu.my/11989/ Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate Halim, S.N.A. Ali, H.M. Ng, S.W. Q Science (General) In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. International Union of Crystallography 2010 Article PeerReviewed Halim, S.N.A. and Ali, H.M. and Ng, S.W. (2010) Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1439-U950. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Halim, S.N.A.
Ali, H.M.
Ng, S.W.
Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
description In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110].
format Article
author Halim, S.N.A.
Ali, H.M.
Ng, S.W.
author_facet Halim, S.N.A.
Ali, H.M.
Ng, S.W.
author_sort Halim, S.N.A.
title Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
title_short Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
title_full Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
title_fullStr Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
title_full_unstemmed Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
title_sort bis[n `-(2-oxo-1h-indol-3-ylidene)furan2-carbohydrazidato-kappa o-3,n `,o `]manganese(ii) n,n-dimethylformide monosolvate monohydrate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/11989/
_version_ 1643689190695632896

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