catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]

catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]

In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion;...

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Main Authors: Han, Yin-Feng, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/11992/
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spelling my.um.eprints.119922019-01-31T04:20:00Z http://eprints.um.edu.my/11992/ catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate] Han, Yin-Feng Ng, S.W. Q Science (General) In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H center dot center dot center dot O hydrogen bonds involving the coordinated and uncoordinated water molecules. International Union of Crystallography 2010 Article PeerReviewed Han, Yin-Feng and Ng, S.W. (2010) catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1431-U884. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Han, Yin-Feng
Ng, S.W.
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
description In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)(4)]center dot 4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H center dot center dot center dot O hydrogen bonds involving the coordinated and uncoordinated water molecules.
format Article
author Han, Yin-Feng
Ng, S.W.
author_facet Han, Yin-Feng
Ng, S.W.
author_sort Han, Yin-Feng
title catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
title_short catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
title_full catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
title_fullStr catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
title_full_unstemmed catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-kappa O-1)neodymium(III)]-mu-oxalato-kappa O-4(1),O-2:O-1 `,O-2 `] tetrahydrate]
title_sort catena-poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine n-oxide-kappa o-1)neodymium(iii)]-mu-oxalato-kappa o-4(1),o-2:o-1 `,o-2 `] tetrahydrate]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/11992/
_version_ 1643689191559659520

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