Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II)
In the crystal structure of the zinc(II) complex of bicine, [Zn(C6H12NO4)(2)], the deprotonated amino acid O,N,O'-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the metal a...
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my.um.eprints.119962019-01-31T04:40:30Z http://eprints.um.edu.my/11996/ Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) Lo, K.M. Ng, S.W. Q Science (General) In the crystal structure of the zinc(II) complex of bicine, [Zn(C6H12NO4)(2)], the deprotonated amino acid O,N,O'-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the metal atom. The metal atom lies on a center of inversion. The uncoordinated carboxylate O atom is hydrogen bonded to the hydroxy groups of adjacent molecules, these two hydrogen bonds leading to the formation of a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Lo, K.M. and Ng, S.W. (2010) Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1485-U1395. ISSN 1600-5368 |
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Q Science (General) Lo, K.M. Ng, S.W. Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
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In the crystal structure of the zinc(II) complex of bicine, [Zn(C6H12NO4)(2)], the deprotonated amino acid O,N,O'-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the metal atom. The metal atom lies on a center of inversion. The uncoordinated carboxylate O atom is hydrogen bonded to the hydroxy groups of adjacent molecules, these two hydrogen bonds leading to the formation of a three-dimensional network. |
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Article |
author |
Lo, K.M. Ng, S.W. |
author_facet |
Lo, K.M. Ng, S.W. |
author_sort |
Lo, K.M. |
title |
Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
title_short |
Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
title_full |
Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
title_fullStr |
Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
title_full_unstemmed |
Bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa O-3,N,O `}zinc(II) |
title_sort |
bis{2-[bis(2-hydroxyethyl)amino]acetato-kappa o-3,n,o `}zinc(ii) |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/11996/ |
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1643689192710995968 |