catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `]
The Sn atom in the title polymeric compound, [Sn(C7H7)(3)-(C8H12NO2S2)](n), exists in a trans-C3O2 trigonal-bipyramidal coordination environment in the two independent formula units. The carboxylate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain runnin...
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International Union of Crystallography
2010
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my.um.eprints.121932019-01-31T04:32:15Z http://eprints.um.edu.my/12193/ catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] Keng, T.C. Lo, K.M. Ng, S.W. Q Science (General) The Sn atom in the title polymeric compound, [Sn(C7H7)(3)-(C8H12NO2S2)](n), exists in a trans-C3O2 trigonal-bipyramidal coordination environment in the two independent formula units. The carboxylate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O-covalent bond by 0.093 (4) angstrom and in the second molecule, the Sn atom is displaced by 0.105 (4) angstrom in the same direction. International Union of Crystallography 2010 Article PeerReviewed Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1222-U510. ISSN 1600-5368 |
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Q Science (General) Keng, T.C. Lo, K.M. Ng, S.W. catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| description |
The Sn atom in the title polymeric compound, [Sn(C7H7)(3)-(C8H12NO2S2)](n), exists in a trans-C3O2 trigonal-bipyramidal coordination environment in the two independent formula units. The carboxylate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O-covalent bond by 0.093 (4) angstrom and in the second molecule, the Sn atom is displaced by 0.105 (4) angstrom in the same direction. |
| format |
Article |
| author |
Keng, T.C. Lo, K.M. Ng, S.W. |
| author_facet |
Keng, T.C. Lo, K.M. Ng, S.W. |
| author_sort |
Keng, T.C. |
| title |
catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| title_short |
catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| title_full |
catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| title_fullStr |
catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| title_full_unstemmed |
catena-Poly[[tribenzyltin(IV)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa O-2/O `] |
| title_sort |
catena-poly[[tribenzyltin(iv)]-mu-2-(piperidin-1ylcarbothioylsulfany l)acetato-kappa o-2/o `] |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/12193/ |
| _version_ |
1643689242356875264 |