Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate
The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-...
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2010
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my.um.eprints.121992019-01-31T05:06:38Z http://eprints.um.edu.my/12199/ Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate Najafi, E. Amini, M.M. Ng, S.W. Q Science (General) The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent molecules are linked by these two hydrogen bonds, generating a chain running along the a axis. International Union of Crystallography 2010 Article PeerReviewed Najafi, E. and Amini, M.M. and Ng, S.W. (2010) Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1278-U1024. ISSN 1600-5368 |
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Q Science (General) Najafi, E. Amini, M.M. Ng, S.W. Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
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The title compound, [ZnBr(C9H6NO)(C9H7NO)]center dot CH3OH, has its metal atom N,O-chelated by a neutral and a deprotonated 8-hydroxyquinoline ligand. The hydroxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alkoxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent molecules are linked by these two hydrogen bonds, generating a chain running along the a axis. |
| format |
Article |
| author |
Najafi, E. Amini, M.M. Ng, S.W. |
| author_facet |
Najafi, E. Amini, M.M. Ng, S.W. |
| author_sort |
Najafi, E. |
| title |
Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_short |
Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_full |
Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_fullStr |
Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_full_unstemmed |
Bromido(quinolin-8-ol-kappa N-2,O)(quinolin-8-olato-kappa N-2,O)zinc(II) methanol monosolvate |
| title_sort |
bromido(quinolin-8-ol-kappa n-2,o)(quinolin-8-olato-kappa n-2,o)zinc(ii) methanol monosolvate |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/12199/ |
| _version_ |
1643689244081782784 |