catena-Poly[[triphenyltin(IV)]-mu(2)-[3-(cyclohexylcarbamoy)propan oato-kappa O-2(1):O-3]]

catena-Poly[[triphenyltin(IV)]-mu(2)-[3-(cyclohexylcarbamoy)propan oato-kappa O-2(1):O-3]]

The Sn atom in the polymeric title compound, [Sn(C6H5)(3)-(C10H16NO3)](n), is five-coordinated within a trans-C3O2 donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain al...

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Bibliographic Details
Main Authors: Shams-ul-Islam, S., Bhatti, M.H., Imtiaz-ud-Din, A., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12203/
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Institution: Universiti Malaya
Description
Summary:The Sn atom in the polymeric title compound, [Sn(C6H5)(3)-(C10H16NO3)](n), is five-coordinated within a trans-C3O2 donor set that defines an approximate trigonal-bipyramidal geometry. The carboxylate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intramolecular carboxylate-carbonyl N-H center dot center dot center dot O hydrogen bond is responsible for the curved conformation within the carboxylate ligand.

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