Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)

Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)

Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Zn(C8H16NS2)(2)-(C12H8N2)]. The N2S4 donor set about Zn is defined by two symmetrically chelating dithiocarbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octahedral coordinati...

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Main Authors: Alzaalouk, A.S., Baba, I., Tahir, M.I.M., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12407/
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spelling my.um.eprints.124072019-01-31T01:26:28Z http://eprints.um.edu.my/12407/ Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II) Alzaalouk, A.S. Baba, I. Tahir, M.I.M. Ng, S.W. Tiekink, E.R.T. Q Science (General) Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Zn(C8H16NS2)(2)-(C12H8N2)]. The N2S4 donor set about Zn is defined by two symmetrically chelating dithiocarbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octahedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetrameric supramolecular aggregates mediated by C-H center dot center dot center dot S interactions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5). International Union of Crystallography 2010 Article PeerReviewed Alzaalouk, A.S. and Baba, I. and Tahir, M.I.M. and Ng, S.W. and Tiekink, E.R.T. (2010) Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1165-U1151. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Alzaalouk, A.S.
Baba, I.
Tahir, M.I.M.
Ng, S.W.
Tiekink, E.R.T.
Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
description Two independent but very similar molecules comprise the asymmetric unit of the title compound, [Zn(C8H16NS2)(2)-(C12H8N2)]. The N2S4 donor set about Zn is defined by two symmetrically chelating dithiocarbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octahedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetrameric supramolecular aggregates mediated by C-H center dot center dot center dot S interactions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)-0.725 (5).
format Article
author Alzaalouk, A.S.
Baba, I.
Tahir, M.I.M.
Ng, S.W.
Tiekink, E.R.T.
author_facet Alzaalouk, A.S.
Baba, I.
Tahir, M.I.M.
Ng, S.W.
Tiekink, E.R.T.
author_sort Alzaalouk, A.S.
title Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
title_short Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
title_full Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
title_fullStr Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
title_full_unstemmed Bis(N-sec-butyl-N-n-propyldithio-carbamato- kappa S-2,S `)(1,10-phenanthroline-kappa N-2,N `)zinc(II)
title_sort bis(n-sec-butyl-n-n-propyldithio-carbamato- kappa s-2,s `)(1,10-phenanthroline-kappa n-2,n `)zinc(ii)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12407/
_version_ 1643689289699033088

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