Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)

Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)

Tris(2-chlorobenzyl) tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecul...

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Main Authors: Keng, T.C., Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
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Q Science (General)
Online Access:http://eprints.um.edu.my/12412/
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spelling my.um.eprints.124122019-01-31T04:31:37Z http://eprints.um.edu.my/12412/ Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1) Keng, T.C. Lo, K.M. Ng, S.W. Q Science (General) Tris(2-chlorobenzyl) tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked to the other molecule by an N-H center dot center dot center dot N hydrogen bond. In the second molecule, two of the chlorobenzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both molecules shows a distorted tetrahedral SnSC(3) coordination. International Union of Crystallography 2010 Article PeerReviewed Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1064-U301. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Keng, T.C.
Lo, K.M.
Ng, S.W.
Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
description Tris(2-chlorobenzyl) tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked to the other molecule by an N-H center dot center dot center dot N hydrogen bond. In the second molecule, two of the chlorobenzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both molecules shows a distorted tetrahedral SnSC(3) coordination.
format Article
author Keng, T.C.
Lo, K.M.
Ng, S.W.
author_facet Keng, T.C.
Lo, K.M.
Ng, S.W.
author_sort Keng, T.C.
title Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
title_short Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
title_full Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
title_fullStr Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
title_full_unstemmed Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-kappa S)tin(IV)-tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-kappa S) tin(IV) (1/1)
title_sort tris(2-chlorobenzyl)(1h-1,2,4-triazole-5-thiolato-kappa s)tin(iv)-tris(2-chlorobenzyl)(4h-1,2,4-triazole-3-thiolato-kappa s) tin(iv) (1/1)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12412/
_version_ 1643689291159699456

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