Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]

Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]

In the centrosymmetric binuclear title compound, [Pb-2(N-3)(2)-( NCS)(2)(C12H8N2)(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thiocyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is...

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Main Authors: Mohammadnezhad, G., Ghanbarpour, A.R., Amini, M.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12413/
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spelling my.um.eprints.124132019-01-31T04:45:57Z http://eprints.um.edu.my/12413/ Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)] Mohammadnezhad, G. Ghanbarpour, A.R. Amini, M.M. Ng, S.W. Q Science (General) In the centrosymmetric binuclear title compound, [Pb-2(N-3)(2)-( NCS)(2)(C12H8N2)(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thiocyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)degrees. The Pb-TT atom is in a Psi-square-antiprismaic coordination. International Union of Crystallography 2010 Article PeerReviewed Mohammadnezhad, G. and Ghanbarpour, A.R. and Amini, M.M. and Ng, S.W. (2010) Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1120-U735. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
description In the centrosymmetric binuclear title compound, [Pb-2(N-3)(2)-( NCS)(2)(C12H8N2)(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thiocyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)degrees. The Pb-TT atom is in a Psi-square-antiprismaic coordination.
format Article
author Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
author_facet Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
author_sort Mohammadnezhad, G.
title Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
title_short Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
title_full Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
title_fullStr Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
title_full_unstemmed Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]
title_sort di-mu-azido-kappa n-4(1):n-1-bis[(1,10-phenanthroline-kappa n-2,n `)(thiocyanato-kappa n)lead(ii)]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12413/
_version_ 1643689291448057856

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