Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate
The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]center dot 0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) A in one ring and by 0.690 (1) A for the other. The two p...
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2010
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my.um.eprints.125432019-01-30T08:41:31Z http://eprints.um.edu.my/12543/ Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate Thy, C.K. Lo, K.M. Ng, S.W. QD Chemistry The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]center dot 0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) A in one ring and by 0.690 (1) A for the other. The two planes are aligned at an angle of 59.6 (1)degrees. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion. International Union of Crystallography 2010 Article PeerReviewed Thy, C.K. and Lo, K.M. and Ng, S.W. (2010) Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M992-U1217. ISSN 1600-5368 |
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QD Chemistry Thy, C.K. Lo, K.M. Ng, S.W. Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| description |
The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]center dot 0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) A in one ring and by 0.690 (1) A for the other. The two planes are aligned at an angle of 59.6 (1)degrees. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion. |
| format |
Article |
| author |
Thy, C.K. Lo, K.M. Ng, S.W. |
| author_facet |
Thy, C.K. Lo, K.M. Ng, S.W. |
| author_sort |
Thy, C.K. |
| title |
Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| title_short |
Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| title_full |
Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| title_fullStr |
Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| title_full_unstemmed |
Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate |
| title_sort |
dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 o,o')tin(iv) toluene hemisolvate |
| publisher |
International Union of Crystallography |
| publishDate |
2010 |
| url |
http://eprints.um.edu.my/12543/ |
| _version_ |
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