(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)

(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)

The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent...

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Main Authors: Wong, H.W., Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12562/
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spelling my.um.eprints.125622019-01-30T08:26:46Z http://eprints.um.edu.my/12562/ (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V) Wong, H.W. Lo, K.M. Ng, S.W. Q Science (General) The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O-H...N hydrogen bond with an N-atom acceptor site. International Union of Crystallography 2010 Article PeerReviewed Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M1021-U1469. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Wong, H.W.
Lo, K.M.
Ng, S.W.
(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
description The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O-H...N hydrogen bond with an N-atom acceptor site.
format Article
author Wong, H.W.
Lo, K.M.
Ng, S.W.
author_facet Wong, H.W.
Lo, K.M.
Ng, S.W.
author_sort Wong, H.W.
title (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
title_short (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
title_full (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
title_fullStr (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
title_full_unstemmed (Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)
title_sort (acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 o,n',o')(methoxo-kappa o)oxidovanadate(v)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12562/
_version_ 1643689325817233408

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