3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one

3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one

The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)degrees]. In the crystal,...

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Main Authors: Zukerman-Schpector, J., De Simone, C.A., Olivato, P.R., Cerqueira, C.R., Santos, J.M.M., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12728/
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spelling my.um.eprints.127282019-01-30T08:16:08Z http://eprints.um.edu.my/12728/ 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one Zukerman-Schpector, J. De Simone, C.A. Olivato, P.R. Cerqueira, C.R. Santos, J.M.M. Tiekink, E.R.T. Q Science (General) The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)degrees]. In the crystal, C-H center dot center dot center dot O interactions link the molecules into [010] supramolecular chains with a helical topology. C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also present. International Union of Crystallography 2010 Article PeerReviewed Zukerman-Schpector, J. and De Simone, C.A. and Olivato, P.R. and Cerqueira, C.R. and Santos, J.M.M. and Tiekink, E.R.T. (2010) 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one. Acta Crystallographica Section E: Structure Reports Online, 66 (7). O1863-U1080. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Zukerman-Schpector, J.
De Simone, C.A.
Olivato, P.R.
Cerqueira, C.R.
Santos, J.M.M.
Tiekink, E.R.T.
3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
description The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)degrees]. In the crystal, C-H center dot center dot center dot O interactions link the molecules into [010] supramolecular chains with a helical topology. C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also present.
format Article
author Zukerman-Schpector, J.
De Simone, C.A.
Olivato, P.R.
Cerqueira, C.R.
Santos, J.M.M.
Tiekink, E.R.T.
author_facet Zukerman-Schpector, J.
De Simone, C.A.
Olivato, P.R.
Cerqueira, C.R.
Santos, J.M.M.
Tiekink, E.R.T.
author_sort Zukerman-Schpector, J.
title 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
title_short 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
title_full 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
title_fullStr 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
title_full_unstemmed 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
title_sort 3,3-bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12728/
_version_ 1643689362546753536

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