[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)

[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)

The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angs...

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Main Authors: Tadbuppa, P.P., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/13220/
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Institution: Universiti Malaya
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spelling my.um.eprints.132202019-04-16T11:42:16Z http://eprints.um.edu.my/13220/ [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I) Tadbuppa, P.P. Tiekink, E.R.T. Q Science (General) The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Tadbuppa, P.P. and Tiekink, E.R.T. (2010) [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I). Acta Crystallographica Section E: Structure Reports Online, 66 (6). M664-U650. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Tadbuppa, P.P.
Tiekink, E.R.T.
[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
description The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. In the crystal structure, molecules are arranged into supramolecular chains along the b axis by C-H center dot center dot center dot pi interactions.
format Article
author Tadbuppa, P.P.
Tiekink, E.R.T.
author_facet Tadbuppa, P.P.
Tiekink, E.R.T.
author_sort Tadbuppa, P.P.
title [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
title_short [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
title_full [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
title_fullStr [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
title_full_unstemmed [(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
title_sort [(z)-o-methyl n-(3-chlorophenyl)thiocarbamato-kappa s](triphenylphosphine-kappa p)gold(i)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/13220/
_version_ 1643689493460418560

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